Applied Mechanics, Vol. 7, Pages 13: Investigation of Microstructure and Mechanical Behavior of Nanomodified Cement-Based Materials

Applied Mechanics doi: 10.3390/applmech7010013

Authors:
Spyridoula G. Farmaki
Dimitrios A. Exarchos
Vasileios Dracopoulos
Anastasios Gkotzamanis
Konstantinos G. Dassios
Theodore E. Matikas

Recent advances in nanotechnology have highlighted the transformative potential of carbon-based nanomaterials, such as carbon nanofibers, carbon nanotubes, and graphene, in cementitious systems. These materials have shown a remarkable ability to enhance the mechanical strength, fracture toughness, and overall functional performance of cementitious composites. Their nanoscale dimensions and exceptional intrinsic properties allow for effective stress bridging, crack arrest, and matrix densification. Despite these promising features, the current understanding remains limited, particularly regarding their application to concrete. Furthermore, literature lacks systematic, parallel evaluations of their respective effectiveness in improving both mechanical performance and long-term durability, as well as their potential to impart true multifunctionality to concrete structures. It is worth noting that significant and statistically significant improvements in fracture behavior were observed at specific nanofiller concentrations, suggesting strong potential for the material system in next-generation innovative infrastructure applications. Experimental results demonstrated that both CNTs and GNPs significantly enhanced the mechanical performance of concrete, with flexural strength increases of approximately 49% and 38%, and compressive strength improvements of 22% and 47%, respectively, at optimum contents of 0.6 wt.% CNTs and 0.8 wt.% GNPs. SEM analyses confirmed improved matrix densification and interfacial bonding at these concentrations, while higher dosages led to agglomeration and reduced performance. This gap highlights the need for targeted experimental studies to elucidate the structure-property relationships governing these advanced materials.

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Spyridoula G. Farmaki www.mdpi.com