Clean Technol., Vol. 7, Pages 30: The Potential to Produce Bio-Based Ammonia Adsorbents from Lignin-Rich Residues

Clean Technologies doi: 10.3390/cleantechnol7020030

Authors:
Daniel Chernick
Valerie Dupont
Andrew B. Ross

The ammonia adsorption capacity of lignin-rich biomass solids was tested for the first time at low partial pressures (<1.5 kPa) and 20 °C. The biomass samples included untreated tree barks, husks, and peats, as well as the biochars produced by their slow pyrolysis. Proximate and ultimate analyses, lignin content, and metal content are also presented. The untreated biosolids had higher VM/FC ratios, molar H/C, and O/C than the treated biosolids (biochars and treated biochars). A novel methodology is described for the safe generation of gaseous ammonia at predictable low partial pressures from tabletop-scale batch reaction experiments of NaOH with (NH4)2SO4 in aqueous solution, leading to the determination of ammonia adsorption capacities from low-cost experiments. Statistically significantly larger NH3 adsorption capacities were obtained for the untreated biosolids than for their biochars (p < 0.001). In contrast, the biochars were found to be poor NH3 adsorbers without further treatment. The NH3 adsorption capacities from this study’s biosolids were compared with those of common adsorbent types in the same conditions using the existing literature through equilibrium model interpolation (Dubinin–Astakhov, Toth, and Freundlich) or cubic spline fit from graphical isotherms. Controls consisting of commercially sourced activated carbons (AC) had low adsorption capacities, close to those derived from the literature in the same conditions for similar materials, confirming the methodology’s robustness. The untreated biosolids’ NH3 adsorption capacities were in the same range as those reported for silica, gamma-alumina, and some of the treated or doped ACs. They also performed better than the undoped, untreated ACs. The work suggests lignin-rich untreated biosolids such as barks and peats are competent low-cost ammonia adsorbents.

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