Materials, Vol. 18, Pages 4313: Sulphate Resistance of Alkali-Activated Material Produced Using Wood Ash

Materials doi: 10.3390/ma18184313

Authors:
Yiying Du
Ina Pundiene
Jolanta Pranckeviciene
Aleksandrs Korjakins

The durability of construction and building materials under sulphate environments is an important indicator to evaluate their service life. In this study, the physical and mechanical behaviours of wood-ash-based alkali-activated materials (AAMs) incorporating coal fly ash, metakaolin, natural zeolite, and calcined phosphogypsum were assessed before and after being subjected to sodium sulphate corrosion cycles via the compressive strength, mass, and volume changes. The microstructure, elemental composition, and phase identification were further analysed using X-Ray Diffraction(XRD) and scanning electron microscope(SEM). The results show that the exposure to sulphate solution caused decalcification and dealumination of hydrates, releasing calcium and aluminium to react with sulphate and forming expansive erosion products, ettringite and gypsum. This contributed to the microstructural damage, leading to mass change, volume expansion, and compressive strength loss of 7.33, 1.29, and 60.42%. The introduction of binary aluminosilicate precursors enhanced the sulphate resistance by forming a well-bonded microstructure consisting of calcium (aluminate) silicate hydrate and sodium aluminate silicate hydrate, with the compressive strength loss decreasing up to 18.60%. The co-usage of calcined phosphogypsum deteriorated the mechanical properties of AAMs but significantly improved the sulphate resistance. The sodium sulphate environment facilitated anhydrate hydration, generating more sulphate hydrates and hemigypsums that co-existed with erosion products, forming a compact microstructure and improving the compressive strength by twofold.

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