Nanomaterials, Vol. 16, Pages 127: Synthesis and Characterization of Nanostructured Thorium Carbide for Radioactive Ion Beam Production

Nanomaterials doi: 10.3390/nano16020127

Authors:
Edgar Reis
Pedro Amador Celdran
Olaf Walter
Rachel Eloirdi
Laura Lambert
Thierry Stora
Simon Stegemann
Doru C. Lupascu
Sebastian Rothe

Thorium carbide (ThC2±x) nano-structured thin disc-like pellets were produced from thoria nanoparticles (ThO2-NP) and multi-walled carbon nanotubes (MWCNT). These composites are to be studied as a target material candidate for radioactive ion beam (RIB) production via nuclear reactions upon impact with high-energy proton beams on a stack of solid pellets. The ThO2-NP precursor was produced via precipitation of thorium oxalate from a thorium nitrate solution with oxalic acid and subsequent hydrothermal oxidation of the oxalate, creating the thoria nanoparticles. The ThO2-NP were then mixed with MWCNT in isopropyl alcohol and sonicated by two different methods to create a nanoparticle dispersion. This dispersion was then heated under medium vacuum to evaporate the solvent; the resulting powder was pressed into pellets and taken to an inert-atmosphere oven, where it was heated to 1650 ∘C and carbothermally reduced to ThC2±x. The resulting pellets were characterized via XRD, SEM-EDS, and Raman spectroscopy. The resulting thorium pellets exhibited, at most, trace levels of the oxide precursor. Furthermore, the nanotube structures were still present in the final product and are expected to contribute positively towards faster radioisotope release times by lowering isotope diffusion times, which is required for the efficient extraction of the shortest-lived (<1 s half-life) radioisotopes.

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Edgar Reis www.mdpi.com