Photonics, Vol. 12, Pages 656: Collaboration of Two UV-Absorbing Dyes in Cholesteric Liquid Crystals Films for Infrared Broadband Reflection and Ultraviolet Shielding

Photonics doi: 10.3390/photonics12070656

Authors:
Mengqi Xie
Yutong Liu
Xiaohui Zhao
Zhidong Liu
Jinghao Zhang
Dengyue Zuo
Guang Cui
Hui Cao
Maoyuan Li

This study developed cholesteric liquid crystal broadband reflective films using zinc oxide nanoparticles (ZnO NPs) and homotriazine UV-absorbing dye (UV-1577) to enhance infrared shielding. Unlike benzotriazole-based UV absorber UV-327, which suffers from volatility and contamination, UV-1577 exhibits superior compatibility with liquid crystals, higher UV absorption efficiency, and enhanced processing stability due to its larger molecular structure. By synergizing UV-1577 with ZnO NPs, we achieved a gradient UV intensity distribution across the film thickness, inducing a pitch gradient that broadened the reflection bandwidth to 915 nm and surpassing the performance of previous systems using UV-327/ZnO NPs (<900 nm). We conducted a detailed examination of the factors influencing the reflective bandwidth. These included the UV-1577/ZnO NP ratio, the concentrations of the polymerizable monomer (RM257) and chiral dopant (R5011), along with polymerization temperature, UV irradiation intensity, and irradiation time. The resultant films demonstrated efficient ultraviolet shielding via the UV-1577/ZnO NPs collaboration and infrared shielding through the induced pitch gradient. This work presents a scalable strategy for energy-saving smart windows.

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