1. Introduction
In the context of the carbon peak and carbon-neutral era, new energy vehicles instead of traditional fuel vehicles can widely alleviate the problems of fossil fuel shortages and environmental pollution. Lithium batteries are often used as power batteries for new energy vehicles due to their advantages, such as low self-discharge rate, no memory effect, and high energy density [
1].
In the process of charging and discharging, lithium batteries generate a large amount of heat, which is prone to leading to the thermal runaway phenomenon in the monomers inside the battery module, resulting in a serious imbalance in the temperature distribution between the individual monomers and localized overheating of the battery packs, which results in a mismatch in the performance of monomers between batteries, and further leads to premature failure of the battery module. Therefore, it is necessary to control the thermal behavior of the battery. Studies have shown that lithium-ion batteries must operate within a strict temperature paradigm range (20–55 °C), and operating outside of this temperature range can cause serious problems for the battery. The optimal operating range temperature is 20–40 °C. In addition, the temperature difference between all batteries should not exceed 5 °C [
2,
3]. A good Battery Thermal Management System (BTMS) improves the safety and life of the power battery, thus optimizing the performance and range of the vehicle.
According to the different cooling media, the battery thermal management system can be categorized into air cooling [
4], liquid cooling [
5], phase-change material cooling [
6], heat pipe cooling [
7], and composite cooling [
8].
Liquid cooling (Minichannel Cold Plate, MCP) utilizes the liquid flow, which can quickly control the battery temperature, and utilizes the rapid heat dissipation of the liquid cooling plate to rapidly dissipate the heat generated by the battery into the environment [
9]. However, the temperature difference between the inlet and outlet parts of its liquid cooling plate is large. Jia [
10] analyzed that the number of pipes had the most significant effect on the average temperature of the liquid-cooling plate, and the pipe height had the least effect. In terms of temperature uniformity, the effects of the number of pipes and coolant flow rate were similar, and both were major influences, and the effects of pipe width and pipe height were similar, and both were minor influences. He [
11] designed a double-layer I-shaped liquid cooling plate. Compared to the serpentine channel, this I-shaped liquid cooling plate can reduce the maximum temperature from 307.02 K to 303.94 K and the standard deviation of the surface temperature from 0.80 K to 0.25 K. Therefore, the I-shaped liquid cooling plate is a good solution to the problem.
The heat pipe-based BTMSs has a simple structure and better temperature uniformity. A vapor chamber (VC), which belongs to the heat pipe family, has a more extensive heat transfer area compared to the traditional heat pipe. Thanks to this, it is capable of achieving heat transfer in a two-dimensional plane, thus offering enhanced heat transfer performance and better temperature uniformity [
12]. Xu [
13] investigated the thermal control effect of S-shaped and U-shaped horizontal wave tubes. They found that the S-shaped tube showed higher cooling capacity, and the maximum temperature difference was reduced by 7.49%. The parallel design allows for a more uniform temperature distribution and lower pressure drop.
At present, it is difficult for a single cooling method to meet the demand of battery pack heat dissipation, and the composite cooling method can synthesize the advantages of a single cooling method, which is the research hotspot of power battery technology [
14]. Zhao [
15] proposed a phase change material (PCM)/microchannel coupled battery thermal management system (BTMS). Compared with liquid-cooled plates, the maximum temperature of the battery increased by 0.2 °C. However, the maximum temperature difference and pressure drop were reduced by 9.3% and 93.7%, respectively, and the volume of the optimized design decreased by 15.6%. Jang [
16] proposed a novel BTMS that combines liquid cooling with a heat pipe. Compared with the liquid-cooled battery module, the maximum temperature of the B-type heat pipe liquid-cooled battery module was reduced by 6.1 °C. Wang [
17] arranged the evaporation section of the L-shaped heat pipe between the square cells and the condensation section in the cooling runners at the bottom of the battery module.
However, the heat transfer performance of the heat pipe is also affected by the temperature rise along the coolant, and the heat pipe has a stronger heat transfer capability near the inlet of the coolant and a poorer heat transfer capability near the outlet of the coolant, which will result in the battery module still having a more pronounced temperature difference in the coolant flow direction.
The composite cooling system (Minichannel Cold Plate-Vapor Chamber, MCP-VC), which is based on the characteristics of the liquid cooling and the equalization plate cooling methods, makes the battery temperature more uniform while controlling the maximum battery temperature. In order to further study and optimize the cooling system of the power battery pack and improve the battery’s homogeneous temperature, based on this, this paper firstly carries out the study of the cooling effect of the liquid cooling plate and analyzes the influence of each design parameter on the heat dissipation, and then uses the liquid cooling plate-mean temperature plate scheme for the power battery heat dissipation, and designs the composite heat dissipation system of the lithium battery.
3. Composite Liquid-Cooling BTMS Design
3.1. Liquid Cooling Plate Heat Transfer Principle
According to the basic method of heat transfer, it can be seen that the liquid-cooling plate heat transfer mainly relies on heat conduction and heat convection [
19]. The heat transfer path is that the battery heat is transferred to the liquid-cooling plate, and the coolant flow in the plate takes away the heat. Among them, heat conduction follows Fourier’s law of thermal conductivity, which is calculated as
where Φ is for the thermal conductivity, λ is for the thermal conductivity of the liquid-cooling plate, A is for the contact area, T is for the temperature, and x is for the thermal distance. According to Formula (6), it can be seen that the liquid cooling plate in the design of the material should be selected with high thermal conductivity and, combined with the economical, currently widely used aluminum liquid cooling plate, where the plate thickness is not easily too large, the liquid cooling plate and the battery contact area are as large as possible.
The energy equation of the battery is shown in Equation (7) [
20],
where ρB is the density of the cell, Cp,B is the specific heat capacity of the cell, and kB is the thermal conductivity of the cell.
The coolant momentum, mass, and energy conservation equations are
where ρw is the coolant density, t is the time, is the coolant velocity vector, μ is the coolant dynamic viscosity, Tw is the coolant temperature, p is the coolant pressure, Cp,w is the specific heat capacity of the coolant, and λw is the coefficient of thermal conductivity of the liquid cooling plate.
The Reynolds equation is
where
Re is the Reynolds number,
V is the coolant flow velocity,
G is the viscosity of the coolant, and
d is the equivalent diameter of the channel. In this paper, the coolant velocity is selected to be 0.04 m/s, and the calculated
Re is 1333, which is less than 2300, so it can be judged that the flow state of the coolant is laminar flow [
21].
3.2. Liquid Cooling Plate Design
Before running numerical simulations, simplify the heat dissipation simulation model by assuming the following:
- (1)
The liquid-cooling plate is homogeneous and isotropic.
- (2)
The thermal conductivity of the liquid-cooling plate and the surface of the battery for convective heat transfer with air is 10 W/(m × K).
- (3)
The fluid is incompressible and stable, and the dynamic viscosity, specific heat capacity, and thermal conductivity are constant.
- (4)
The thermal material properties of fluids and solids are independent of temperature.
Here are the initial model boundary conditions:
- (1)
The inlet boundary condition is the velocity inlet boundary condition. We assume a uniform inlet velocity of the coolant and an inlet temperature of 25 °C.
- (2)
The outlet boundary condition suppresses backflow at the outlet end, as it is a pressure boundary condition. Since the fluid is incompressible and its nature is constant, only the relative value of pressure can be considered.
The heat generated by the battery is transferred to the top of the equalization plate through the contact surface of the equalization plate, and the liquid cooling plate is placed on the top of the equalization plate, arranged as shown in
Figure 2. the external dimensions of the liquid cooling plate are the same as that of the battery, with a wall thickness of 4 mm, and the cooling medium is selected as liquid water.
3.3. Orthogonal Experiment
There are many factors that affect the cooling effect of the liquid cooling plate; in this paper, we will focus on four: the width of the cooling channel (A), the height of the cooling channel (B), the number of the cooling channel (C), and the coolant velocity (D). We take four different level values within reasonable limits for each factor, and the optimization aims to reduce the system temperature and temperature difference. Therefore, we chose the average temperature and temperature difference of the liquid-cooling plate as the indexes for this orthogonal experimental design. Because there are four degrees of freedom in the problem, and the factors interact in complex ways, it takes a lot of experiments to find the best set of parameters. A four-level, four-factor orthogonal table was designed as shown in
Table 2. As shown in
Table 2, each row represents a set of parameter structures of liquid-cooling plates, and 16 models are built according to the different parameter structures in each row.
3.4. Grid Independence
The structures for the battery thermal management system are more regular, so the quadrilateral and hexahedral structured grids are used for the whole model. In order to investigate the grid independency of simulation results, grids with 149,386, 195,384, 236,268, 268,581, 331,015, 405,189, 470,508 and 510,256 elements, respectively, are generated for the cooling channel model, which is tested in FLUENT.
It is found that the deviations of the average temperature, temperature difference, and channel pressure drop of the last three are all less than 1%. It can be concluded that the results of the last three grid cells are independent of the number of grids. Therefore, considering the solution accuracy and less convergence time, the sixth type of grid cell is selected for numerical research. The grid-independent results are shown in
Figure 3.
3.5. Orthogonal Experimental Scheme and Analysis
16 test models were simulated, and the data of the results were analyzed and sorted. Then
Tave and Δ
Tmax of the battery for each example are calculated, as shown in
Table 3.
Levels can be selected on the basis of kinship. The greater the
Ri, the greater the influence of the factor on the evaluation indicator. The correlation formula for
Ri is as follows:
where i is 1, 2, 3, 4, representing factors A, B, C, and D, respectively; n is 1, 2, 3, and 4, representing four levels, respectively. m is 1 and 2, representing the indicators ΔTave and ΔTmax, respectively. kmn denotes the sum of the evaluation indicators of factor i at n levels.
The impact of the level on the evaluation indicators can be judged directly from the value of the standard deviation (
Si), making the importance of the factor quantifiable. The formula is shown in the following equation:
The effects of four factors, A, B, C, and D, on the mean temperature and temperature difference were obtained by polar analysis as shown in
Figure 4 and
Figure 5.
As shown in
Table 4, for the average temperature, the
Ri and
Si of factor D are the largest, and the
Ri and
Si of factor C are the smallest, so the influence of each factor on the average temperature is in the order of D > B > A > C. The optimal combination of factors for the average temperature index is width 15 mm, height 8 mm, number of rows 5, and the flow rate 0.04 m/s. The trend of the change in the average temperature under each factor is shown in
Figure 2, and the trend is decreasing with the increase in the rank. From the overall trend, the average temperature showed a decreasing trend with the increase in the grade. Therefore, factors A, B, and D can be maximized as far as the practical situation allows.
For the temperature difference, the Ri and Si of factor D are the largest, and the Ri and Si of factor B are the smallest, so the influence of each factor on the temperature difference is in the order of D > C > A > B. The optimal combination under the index for the temperature difference is 11 mm in width, 8 mm in height, four rows, and a flow rate of 0.01 m/s. The trend of the temperature difference under the factors is shown in
Figure 5. It can be seen that with the increase in the level, factor B and factor D generally show the trend of increasing first and then decreasing. When the channel height is 8 mm, factor B minimizes the temperature difference. For factor D, the temperature difference is the smallest when the coolant flow rate is 0.1 m/s, but the average temperature is the largest at this time. We should follow preference when selecting the optimal level for factor A based on the average temperature index. When factor C is selected as 5, 6, and 7, the difference in average temperature is not significant, but the temperature difference is the smallest when the number of runner rows is seven.
In summary, the optimal levels should be taken as A4, B4, C4, and D4.
3.6. Optimized Liquid-Cooling Plate Structure
As depicted in
Figure 6, the orthogonal experiments reveal that the relatively optimal combination model 17, with dimensions of 15 mm in width and 8 mm in height, controls the average temperature at a lower level than the other 16 groups. When the model is 15 mm in width, 8 mm in height, has seven rows, and has a 0.04 m/s flow rate, the average temperature of the cell is 31.89 °C, and the temperature difference is 2.85 °C.
3.7. Composite Liquid-Cooling Structure
In this paper, a power battery thermal management scheme using a composite of a liquid-cooling plate and a Vapor chamber is proposed, and a Vapor chamber is arranged between the battery and the liquid-cooling plate, as shown in
Figure 1 for model 18 (MCP-VC). The equivalent thermal conductivity of the Vapor chamber is 5000 W/(m × K).
The average temperature of model 18 is 32.42 °C, and the temperature difference is 1.40 °C. Compared with model 17 (MCP), the average temperature increases by 1.65%, and the temperature difference decreases by 50.83%.
The cell cross-section temperature distributions of the two cooling structures are presented in
Figure 7, visually demonstrating the differences in temperature uniformity between the two cases.
4. Experiment
4.1. Experimental Equipment
Experiment-related test equipment includes the Xinwei (China) CT-4004-5V100A-NFA charge/discharge system, Topray (China) TP700 temperature acquisition system, T-type thermocouples, Shanghai YIHE (China) scientific thermostatic box, Jieheng (China) KY-300EA peristaltic pump, upper computer, liquid-cooling plate, as well as the homogeneous temperature plate.
Figure 8 displays the schematic diagram of the experimental setup. The blue line depicts the coolant inflow, while the red line depicts the coolant outflow.
4.2. NC Experimental Validation
A battery tester was used to operate the soft pack lithium battery at a 2C discharge multiplication rate. The lithium battery was placed in a thermal chamber at 25 °C, and eight main temperature test points were arranged according to the heat generation-heat transfer mechanism and temperature distribution characteristics of the lithium-ion battery to reflect the overall temperature change in the battery. Test point locations: battery front negative end (test point 1), battery front positive end (test point 2), battery front center (test point 3), battery front center corresponding to the bottom (test point 4), battery back negative end (test point 5), battery back positive end (test point 6), battery back center (test point 7), and battery back center corresponding to the bottom (test point 8). The temperature data from the thermocouples were collected using the Topray TP700 temperature collector and transferred to the computer. The average temperature measured by the eight thermocouples was used as the experimental value, and the average value of the temperature on the middle surface of the battery was used as the simulation temperature value.
Figure 9 demonstrates the comparison between the experimental and simulation results under natural convection (NC). As shown in
Figure 9, the curves of simulation and experiment are in good agreement, and the maximum relative error is not more than 3.5%. When the battery is discharged at 2C multiplicity, the maximum average temperature of the battery exceeds 45 °C. Therefore, an efficient BTMS needs to be designed to reduce the battery temperature.
The simulation defines the battery as a solid heat source, and the temperature difference is tiny, at 0.76 °C in the NC simulation. In fact, the positive pole of the battery generates heat, so the highest point of the experimental temperature is point 6, and the lowest point of the temperature is point 8.
4.3. Experimental Validation of MPC and MCP-VC
We placed the cooling device in a thermal chamber at 25 °C.
Figure 10 shows that the cooling device was covered with 1 mm of silicone grease that has a thermal conductivity of 2 W/(m × K) between the battery and the Vapor chamber to make it fit better. At a temperature of 25 °C, the coolant flow rate was 0.04 m/s.
The simulation and experimental results are shown in
Figure 11; the average temperature of the MCP experiment is 35.95 °C, and the maximum temperature difference is 3.98 °C; the average temperature of the MCP-VC experiment is 35.13 °C, and the maximum temperature difference is 3.69 °C. The average temperature decreased by 2.3%, and the temperature difference decreased by 7.2%, with the same trend as the simulation results. The experimental temperatures are all higher than the simulation temperature, presumed to be the incomplete fitting between the structures and the presence of air with low thermal conductivity, which affects the cooling effect.
4.4. Experimental Validation of MCP-VC at Different Coolant Speeds
In both modes of MCP cooling and MCP-VC cooling, the average temperature decreases with increasing coolant velocity, and the temperature difference increases with increasing coolant velocity.
Figure 12 displays that the average temperature dropped by 10% when the speed of the coolant was raised from 0.01 m/s to 0.04 m/s in the experimental case. The average temperature of MCP-VC was lower than that of the MCP mode at any coolant velocity. The temperature differences between the MCP-VC mode and the MCP mode at coolant velocities of 0.01 m/s, 0.02 m/s, 0.03 m/s, and 0.04 m/s were significantly different from the slow rise in temperature difference in the MCP mode. This was because the lowest point of the cells’ temperatures changed. For the first two groups, it was point 4, which is in the middle of the cell’s frontal side and corresponds to the bottom; for the third group, it was point 1, which is the cell front negative bottom.
4.5. Low-Temperature Preheating Analysis
The model employed for the preheating simulation, which encompasses the liquid, the cooling plate, and the Vapor chamber, is identical to the numerical model utilized in the cooling simulation. The ambient temperature is −10 °C. The coolant inlet temperatures are 15 °C, 20 °C, 25 °C, and 30 °C, and the flow rate is 0.04 m/s.
Numerical simulation results (
Figure 13) demonstrate that the warm-up process decelerates as the coolant temperature drops. For batteries with coolant temperatures of 15 °C, 20 °C, 25 °C, and 30 °C, it takes 894 s, 651 s, 524 s, and 448 s, respectively, to heat the battery to 5 °C. The results suggest that increasing the coolant temperature enables the battery module to be pre-heated more rapidly.
The temperature difference during the preheating process will first increase, then decrease, and finally stabilize. When the inlet temperatures of the heating medium are 15 °C, 20 °C, 25 °C, and 30 °C, the times required for the MCP-VC to reduce the temperature difference to 5 °C during the preheating process are 669 s, 843 s, 1029 s, and 1269 s, respectively.
Elevating the temperature of the heating medium can significantly enhance the preheating capacity while shortening the preheating duration. However, a relatively high temperature of the heating medium leads to greater energy consumption and a longer time to meet the requirement for temperature uniformity.